This book highlights the failure theories and evaluation techniques of thermal barrier coatings, covering the thermal-mechanical–chemical coupling theories, performance and damage characterization techniques, and related evaluations. Thermal barrier coatings are the key thermal protection materials for high-temperature components in advanced aeroengines. Coating spallation is a major technical bottleneck faced by researchers. The extremely complex microstructure, diverse service environments, and failure behaviors bring challenges to the spallation analysis in terms of the selective use of mechanical theories, experimental methods, and testing platforms. In the book, the authors provide a systematic summary of the latest research and technological advances and present their insights and findings in the past couple of decades. This book is not only suitable for researchers and engineers in thermal barrier coatings and related fields but also a good reference for upper-undergraduate and postgraduate students of materials science and mechanics majors.