This book constitutes the refereed proceedings of the 14th International Workshop on Post-Quantum Cryptography, PQCrypto 2022, held in College Park, MD, USA, in August 14–18, 2023. The 25 full papers presented in this book were carefully reviewed and selected from 51 submissions. They are categorized in the following topical sections: code-based cryptography; group-action-based cryptography; isogenye-based cryptography; lattice-based cryptography; multivariate cryptography; quantum algorithms, cryptanalysis and models; post-quantum protocols; side channel cryptanalysis and countermeasures.