This volume presents peer-reviewed surveys on new developments in the study of Lyapunov exponents in dynamical systems and its applications to other areas, such as mathematical physics. Written by leading experts in their fields, the contributions are based upon the presentations given by invited speakers at the “New Trends in Lyapunov Exponents” workshop held in Lisbon, Portugal, February 7–11, 2022. The works focus on the concept of Lyapunov exponents in their various manifestations in dynamical systems along with their applications to mathematical physics and other areas of mathematics. The papers reflect the spirit of the conference of promoting new connections among different subjects in dynamical systems. This volume aims primarily at researchers and graduate students working in dynamical systems and related fields, serving as an introduction to active fields of research and as a review of recent results as well.